SCHEDULED MAINTENANCE
The kinetics of the photoinduced decomposition of solid Na[ClO4] and Na[ClO3] have been derived from X-ray photoelectron spectroscopic data. Sodium perchlorate is shown to undergo reduction to the chloride via sodium chlorate in a consecutive first-order process, and evidence for a defect surface NaCl phase is presented.
R. G. Copperthwaite and J. Lloyd, J. Chem. Soc., Dalton Trans., 1977, 1117 DOI: 10.1039/DT9770001117
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