Issue 9, 1977

Hydrolysis of magnesium(II) in 1.0 mol dm–3 aqueous (Na,H)NO3 solution

Abstract

Hydrolysis of magnesium(II) has been studied in 1.0 mol dm–3(Na,H)NO3 aqueous solution at 25.0 °C by means of e.m.f. measurements of a cell containing suitable test solutions. Magnesium(II) is hydrolyzed to form polynuclear complexes [Mg2(OH)2]2+(log β22–22.07) and [Mg3(OH)4]2+(log β34–39.06). The formation of these species can be accounted for by the ‘truncated-core-plus-links’ expression.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 912-914

Hydrolysis of magnesium(II) in 1.0 mol dm–3 aqueous (Na,H)NO3 solution

H. Einaga, J. Chem. Soc., Dalton Trans., 1977, 912 DOI: 10.1039/DT9770000912

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