Issue 4, 1977

Crystal and molecular structure of a paramagnetic hydridotetrahydro-borato-complex of cobalt: hydridotetrahydroboratobis(tricyclohexylphosphine)cobalt

Abstract

The crystal structure of the title compound has been determined by single-crystal X-ray diffraction techniques. Crystals are monoclinic, space group P21/a. with cell dimension a= 23.391 (10). b= 12.614(4), c= 13.195(6)Å, β= 106.93(3)°Z= 4. The cobalt atom is co-ordinated by two tricyclohexylphosphine ligands in the trans-positions, a hydride hydrogen, and two bridging hydrogen atoms of the tetrahydroborato-ligands in a deformed square pyramid.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1977, 385-388

Crystal and molecular structure of a paramagnetic hydridotetrahydro-borato-complex of cobalt: hydridotetrahydroboratobis(tricyclohexylphosphine)cobalt

M. Nakajima, T. Saito, A. Kobayashi and Y. Sasaki, J. Chem. Soc., Dalton Trans., 1977, 385 DOI: 10.1039/DT9770000385

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