Cysteine peptides react with iron(III) chloride in dimethyl sulphoxide in the presence of base to form rubredoxin analogues (2), which are converted by addition of aqueous sodium sulphide into four-iron ferredoxin analogues (4).
G. Christou, B. Ridge and H. N. Rydon, J. Chem. Soc., Chem. Commun., 1977, 908 DOI: 10.1039/C39770000908
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