The antibiotic anticapsin (8) has been synthesised by a route involving Michael addition of methyl nitro-acetate to 4-methylenecyclohex-2-enone (1) and enzymic deacylation of the derived (±)-N-acetylanticapsin methyl ester (7).
R. W. Rickards, J. L. Rodwell and K. J. Schmalzl, J. Chem. Soc., Chem. Commun., 1977, 849 DOI: 10.1039/C39770000849
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