Issue 21, 1977

Transition metal-catalysed rearrangement of allyl but-3-enoate to hepta-2,6-dienoic or hepta-3,6-dienoic acids

Abstract

The rearrangement of allyl but-3-enoate to heptadienoic acids is catalysed by nickel and rhodium complexes in the presence of phosphorus-containing ligands and can be driven towards either the 2,6- or the 3,6-isomers through selective hydrogen abstraction.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 793-794

Transition metal-catalysed rearrangement of allyl but-3-enoate to hepta-2,6-dienoic or hepta-3,6-dienoic acids

G. P. Chiusoli, G. Salerno and F. Dallatomasina, J. Chem. Soc., Chem. Commun., 1977, 793 DOI: 10.1039/C39770000793

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