Alkali-metal ions caused an acceleration of the reaction between N-propyl-1,4-dihydronicotinamide and Fe(CN)63– in the decreasing order Cs+ > Rb+ > K+ > Na+ > Li+=ca. Et4N+, which suggests the acceleration of the electron-transfer process by polarizable alkali-metal ions.
T. Okamoto, A. Ohno and S. Oka, J. Chem. Soc., Chem. Commun., 1977, 784 DOI: 10.1039/C39770000784
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