Issue 20, 1977

Stereochemistry of the SN2′ reaction in cyclohex-2-enyl esters

Abstract

The SN2′ displacement of the cyclohex-2-enyl esters (1), (2), and (5) by piperidine proceeds with syn stereochemistry; the apparent anti products originate by SN2 reaction of the rearranged esters (15), (12), and (14).

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 722-723

Stereochemistry of the SN2′ reaction in cyclohex-2-enyl esters

A. A. Dobbie and K. H. Overton, J. Chem. Soc., Chem. Commun., 1977, 722 DOI: 10.1039/C39770000722

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