Issue 20, 1977

Investigation by deuterium-labelling of the isomerisation of dihydroxyalkyl radicals formed upon photolysis of cobaloxime complexes

Abstract

Anaerobic photolysis of 5-deuterio-4,5-dihydrooxyhexyl(pyridine)cobaloxime at pH 3 gives 2-deuteriohexanal and probably 6-deuteriohexan-2-one.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 693-694

Investigation by deuterium-labelling of the isomerisation of dihydroxyalkyl radicals formed upon photolysis of cobaloxime complexes

B. T. Golding, C. S. Sell and P. J. Sellars, J. Chem. Soc., Chem. Commun., 1977, 693 DOI: 10.1039/C39770000693

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