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Issue 19, 1977
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Evidence for C–C σ-delocalisation in simple secondary carbonium ions; secondary → primary rearrangements

Abstract

Small yields of primary acetates are obtained in the acetolysis of typical secondary N-alkyl-N-nitrosoacetamides; they imply strongly endothermal rearrangements in the cationic intermediates, best explained by C–C σ-delocalisation or ‘non-classicism.’

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Article information


J. Chem. Soc., Chem. Commun., 1977, 668-669
Article type
Paper

Evidence for C–C σ-delocalisation in simple secondary carbonium ions; secondary → primary rearrangements

C. M. Copper, P. J. Jenner, N. Perry, H. Storesund, J. Russell-King and M. C. Whiting, J. Chem. Soc., Chem. Commun., 1977, 668
DOI: 10.1039/C39770000668

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