SCHEDULED MAINTENANCE
Small yields of primary acetates are obtained in the acetolysis of typical secondary N-alkyl-N-nitrosoacetamides; they imply strongly endothermal rearrangements in the cationic intermediates, best explained by C–C σ-delocalisation or ‘non-classicism.’
C. M. Copper, P. J. Jenner, N. Perry, H. Storesund, J. Russell-King and M. C. Whiting, J. Chem. Soc., Chem. Commun., 1977, 668 DOI: 10.1039/C39770000668
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