Pseudo-rotation in seven-co-ordination: implications in catalysis. X-Ray crystal structure of [HMo(C2H4)2(cis-Ph2PCH
CHPPh2)2]+
Abstract
The seven-co-ordinate complex, [HMo(C2H4)2-(cis-Ph2PCH
CHPPh2)]+, is pentagonal bipyramidal both in solution and in the solid state, and undergoes internal rearrangement by a pseudo-rotation process.
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CHPPh2)2]+