Issue 18, 1977

Interception of a metallo-intermediate in the oxidation of a bis-hydrazone: reactions of benzil (toluene-p-sulphonyl)hydrazones with lead(IV) and mercury(II) acetates

Abstract

Oxidation of benzil bis(toluene-p-sulphonyl)-hydrazone with mercuric acetate or lead tetra-acetate gave 4,5-diphenyl-1,2,3-triazol-1-yl-toluene-p-sulphon-amide; an unstable hydrazono–mercury acetate intermediate was isolated from the oxidation and comparative evidence for a subsequent diazo intermediate is presented.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 622-623

Interception of a metallo-intermediate in the oxidation of a bis-hydrazone: reactions of benzil (toluene-p-sulphonyl)hydrazones with lead(IV) and mercury(II) acetates

R. N. Butler and A. B. Hanahoe, J. Chem. Soc., Chem. Commun., 1977, 622 DOI: 10.1039/C39770000622

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