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The electronic structure of the H2P–NH2 molecule has been calculated using a pseudopotential method, considering independently the HNP and HNH, then the HPN and HPH angles; the optimized geometry corresponds to a gauche conformation in which the nitrogen atom is pyramidal (sum of bond angles 347°).
M. Barthelat, R. Mathis and F. Mathis, J. Chem. Soc., Chem. Commun., 1977, 615 DOI: 10.1039/C39770000615
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