Single crystal X-ray structure analysis of potassium tetrafluorochromate(III) has shown the anion to consist of approximately planar [Cr3F9] units linked into columns by fluorine bridges, with the columns separated by potassium ions, consistent with the extraordinary ease of cleavage of the crystals into fibres.
J. C. Dewan and A. J. Edwards, J. Chem. Soc., Chem. Commun., 1977, 533 DOI: 10.1039/C39770000533
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