Issue 14, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Diketen as a butenoic acid synthon in regioselective olefin syntheses

Kenji Itoh,   Mitsuyo Fukui  and  Yasuo Kurachi  

Abstract

The adduct (2) between diketen (1) and Me3SiCH2MgCl is a versatile methylbutenoic (isoprenoid) acid synthon in allylation with prenyl bromide, in δ-lactone formation with several carbonyl compounds, and in palladium-mediated alkylation.

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Article information

DOI
https://doi.org/10.1039/C39770000500
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 500-501

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Diketen as a butenoic acid synthon in regioselective olefin syntheses

K. Itoh, M. Fukui and Y. Kurachi, J. Chem. Soc., Chem. Commun., 1977, 500 DOI: 10.1039/C39770000500

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