The first examples of optically active arene–ruthenium complexes (+)-(1) and (–)-(1), prepared by the stepwise reaction of benzene(dichloro)ruthenium dimer with dimethylmercury and (R)-(+)-Ph2-PNHCH(Me)Ph and separated by chromatography, have stable configurations even in solution at 60 °C.
H. Brunner and R. G. Gastinger, J. Chem. Soc., Chem. Commun., 1977, 488 DOI: 10.1039/C39770000488
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