The conversion of 3-carboxymuconolactone (2) into 3-oxoadipic acid (5), catalysed by a cell-free preparation from Neurospora crassa, has been shown, by deuterium labelling, to involve an intramolecular, 1,3-suprafacial hydrogen shift consistent with an initial, allylic isomerisation of the substrate.
R. A. Hill, G. W. Kirby and D. J. Robins, J. Chem. Soc., Chem. Commun., 1977, 459 DOI: 10.1039/C39770000459
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