The metal–carbon bonds in tetramethylgermanium have been preserved during direct fluorination; tetrakis(trifluoromethyl)germanium has been produced from the controlled reaction of elemental fluorine with tetramethylgermanium.
E. K. Liu and R. J. Lagow, J. Chem. Soc., Chem. Commun., 1977, 450 DOI: 10.1039/C39770000450
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