Issue 12, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Barrier to recemization of the framework of a chiral polynuclear cation

Agapios Agapiou,   S. Erik Pedersen,   Leonard A. Zyzyck  and  Jack R. Norton  

Abstract

The framework of the chiral polynuclear cation [Rh{Fe(PAr2)(CO)2(η-C5H5)}2]+(2) racemizes with simultaneous bridge-terminal carbonyl exchange, ΔG‡ being ca. 13 kcal mol–1 in CD2Cl2 for both processes.

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Article information

DOI
https://doi.org/10.1039/C39770000393
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 393-394

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Barrier to recemization of the framework of a chiral polynuclear cation

A. Agapiou, S. E. Pedersen, L. A. Zyzyck and J. R. Norton, J. Chem. Soc., Chem. Commun., 1977, 393 DOI: 10.1039/C39770000393

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