Inversion isomers of 1-fluoro-2,3-cis-dimethyl-cyclopropyl radicals have been observed separately by e.s.r. spectroscopy; the hyperfine splitting constant (h.f.s.c.) of the β-proton cis to the odd electron orbital is far larger than that of the trans β-proton.
T. Kawamura, M. Tsumura and T. Yonezawa, J. Chem. Soc., Chem. Commun., 1977, 373 DOI: 10.1039/C39770000373
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