The homogeneous catalyst system, [Re(CO)5Cl]–EtAlCl2 was found to promote the polymerization of cyclohexene to a molecular weight of ca. 2500; n.m.r. and i.r. spectroscopic evidence indicates that the polymer is completely saturated and the rings are retained.
M. F. Farona and C. Tsonis, J. Chem. Soc., Chem. Commun., 1977, 363 DOI: 10.1039/C39770000363
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