X-ray structural studies of the phenyl thio- and seleno-imines derived from 2,4-xylenol reveal, in both molecules, a syn configuration with X ⋯ O distances of 2·604 Å(X = S) and 2·575 Å(X = Se).
A. Atkinson, A. G. Brewster, S. V. Ley, R. S. Osborn, D. Rogers, D. J. Williams and K. A. Woode, J. Chem. Soc., Chem. Commun., 1977, 325 DOI: 10.1039/C39770000325
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