The reaction of N-(5-chloropyridin-2-yl)-N′N′-dialkylthioureas with phenacyl bromides yields trisubstituted thiazoles via a 1,3-pyridyl shift; the X-ray crystal structure of one of these, 5-(5-chloropyridin-2-yl)-2-diethylamino-4-phenylthiazole, has been determined.
D. J. Le Count and J. A. J. Jarvis, J. Chem. Soc., Chem. Commun., 1977, 282 DOI: 10.1039/C39770000282
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