Issue 7, 1977
From the journal:

Journal of the Chemical Society, Chemical Communications

Formation of chlorobisethylenediaminecobalt(III)-µ-cyano-pentacyanocobalt(III) and the high apparent nucleophile efficiency of the cyanide ligands of hexacyanocobaltate(III)

Michael G. Burnett  and  Alexander D. McMaster  

Abstract

At 25°C with a pH of 7–8 and in concentrations of ca. 10–2M, [Co(CN)6]3– competes successfully with solvent H2O in the substitution of Cl– in trans-[Co(en)2Cl2]+ to give mainly [Co(en)2Cl(µ-CN)Co(CN)5]–(en = ethylenediamine); at higher temperatures polymeric species are also formed.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/C39770000200
Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 200-201

Permissions

Request permissions

Formation of chlorobisethylenediaminecobalt(III)-µ-cyano-pentacyanocobalt(III) and the high apparent nucleophile efficiency of the cyanide ligands of hexacyanocobaltate(III)

M. G. Burnett and A. D. McMaster, J. Chem. Soc., Chem. Commun., 1977, 200 DOI: 10.1039/C39770000200

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements