Issue 5, 1977

Stoicheiometric reduction of activated olefins by co-ordinated and free tertiary alkyl phosphines

Abstract

Activated olefins, HR1C[double bond, length half m-dash]CR1H (R1= CO2Me or COPh), are reduced rapidly and stoicheiometrically by some alkyl phosphines, PR32, (R2= Et, Prn, or Bun), both free and initially bound to cobalt, in anhydrous methanol; the reaction proceeds by the formation of an ylide.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1977, 155-156

Stoicheiometric reduction of activated olefins by co-ordinated and free tertiary alkyl phosphines

M. G. Burnett, T. Oswald and B. J. Walker, J. Chem. Soc., Chem. Commun., 1977, 155 DOI: 10.1039/C39770000155

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