Benzothiet, the parent member of a new class of compounds, has been obained by the vacuum flash pyrolysis of benzo[b]thiophen 1,1-dioxide; it is fairly stable at room temparature but dimerizes above 100 °C giving 6H,12H-dibenzo[b,f][1,5]dithiocin.
W. J. M. van Tilborg and R. Plomp, J. Chem. Soc., Chem. Commun., 1977, 130 DOI: 10.1039/C39770000130
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