Molecular mechanics calculations reproduce the free energy differences between pairs of substituted γ-butyrolactones and allow an interpretation of the observation that germacranolides containing lactonizable α-oriented oxygen functions at C(6) and C(8) preferentially relactonize at C(8).
M. H. P. Guy, G. A. Sim and D. N. J. White, J. Chem. Soc., Perkin Trans. 2, 1976, 1917 DOI: 10.1039/P29760001917
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