The second-order kinetics of the oxidation of some aryldimethylamines with lead tetra-acetate in chloroform-acetic anhydride (1 :1 v/v) to give acetamides and formaldehyde follow the equation –d[LTA]/dt=k[LTA][amine]. The obtained ρ value (–2.4 ± 0.5) is consistent with the presence of a positive charge in the transition state.
G. Galliani, B. Rindone and P. L. Beltrame, J. Chem. Soc., Perkin Trans. 2, 1976, 1803 DOI: 10.1039/P29760001803
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