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Issue 14, 1976
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Organic anions. Part 1. Equilibration of 1,3-diarylpropenes

Abstract

A number of 1,3-diarylpropenes, potential precursors of the allylic anions (I). have been synthesised, and the base catalysed equilibration between the double bond isomers (II) and (III) has been investigated. The equilibrium constants correlate satisfactorily with the substituent constant σ. N.m.r. shift reagents aided spectroscopic analysis of certain mixtures.

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Article information


J. Chem. Soc., Perkin Trans. 2, 1976, 1683-1688
Article type
Paper

Organic anions. Part 1. Equilibration of 1,3-diarylpropenes

R. J. Bushby and G. J. Ferber, J. Chem. Soc., Perkin Trans. 2, 1976, 1683
DOI: 10.1039/P29760001683

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