Issue 13, 1976

Enthalpies of transfer involving ionic transition states : the redundance of extrathermodynamic assumptions

Abstract

It is pointed out that the calculation of transition state enthalpies of transfer for reactions involving ions does not necessitate the estimation of thermodynamic quantities for single ions. The procedure is illustrated by data on the reaction between ethyl acetate and sodium hydroxide in water–dimethyl sulphoxide mixtures.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1976, 1531-1532

Enthalpies of transfer involving ionic transition states : the redundance of extrathermodynamic assumptions

V. Gold, J. Chem. Soc., Perkin Trans. 2, 1976, 1531 DOI: 10.1039/P29760001531

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