Rate constants and activation parameters for the addition of mesitonitrile oxide to cis- and trans- cyclo-octene have been determined. It is concluded that the high reactivity of trans-cyclo-octene with mesitonitrile oxide and other 1,3-dipoles is due to distortions of the double bond.
G. Bianchi and D. Maggi, J. Chem. Soc., Perkin Trans. 2, 1976, 1030 DOI: 10.1039/P29760001030
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