SCHEDULED MAINTENANCE
The enthalpy and entropy changes for the interconversion both of the tight and loose ion-pairs of a wide variety of carbanions are related by the equation ΔH=αΔS+β where α and β are constants characteristic of the solvent and the cation. A simple electrostatic treatment gives a qualitative explanation of this effect.
G. C. Greenacre and R. N. Young, J. Chem. Soc., Perkin Trans. 2, 1976, 874 DOI: 10.1039/P29760000874
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