Issue 5, 1976

Reactions of radical anions. Part XVI. Interpretation of the hyperfine coupling constants of 31P nuclei in phosphorus-containing radical anions

Abstract

We have correlated the observed phosphorus coupling constants of five radical anions obtained from phosphine derivatives with the calculated spin densities, and find that dπpπ interactions account satisfactorily for the results whereas pπpπ interactions give results very different from those observed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1976, 492-497

Reactions of radical anions. Part XVI. Interpretation of the hyperfine coupling constants of 31P nuclei in phosphorus-containing radical anions

A. G. Evans, J. C. Evans and D. Sheppard, J. Chem. Soc., Perkin Trans. 2, 1976, 492 DOI: 10.1039/P29760000492

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