Issue 3, 1976

Conformational equilibria and barriers to rotation in monohalogenobutanes with methyl substituents. Methyl–halogen interactions. The size of a halogen atom

Abstract

An n.m.r. study of barriers to rotation and conformational equilibria in 2-halogeno-2, 3, 3-trimethylbutanes and 2-halogeno-2, 3-dimethylbutanes is reported. Results are discussed in terms of the steric requirement of halogen atoms, and the interaction of these atoms with adjacent methyl groups.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1976, 336-341

Conformational equilibria and barriers to rotation in monohalogenobutanes with methyl substituents. Methyl–halogen interactions. The size of a halogen atom

J. E. Anderson, C. W. Doecke and H. Pearson, J. Chem. Soc., Perkin Trans. 2, 1976, 336 DOI: 10.1039/P29760000336

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