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The labelling pattern has been partially determined for the sesquiterpenoid culmorin when biosynthesized from [2-3H2,2-14C]-, (2S)-[2-3H,2-14C]-, (4R)-[4-3H,2-14C]-, [5-3H2,2-14C]-, and (5R)-[5-3H,2-14C]-mevalonic acid by Fusarium culmorum. The results are discussed in terms of the cyclization of farnesyl pyrophosphate.
J. R. Hanson and R. Nyfeler, J. Chem. Soc., Perkin Trans. 1, 1976, 2471 DOI: 10.1039/P19760002471
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