SCHEDULED MAINTENANCE:
3-Hydroxypyridine, its 6-methyl analogue, and 4-hydroxyisoquinoline all react with 2 mol. equiv. of benzyne cycloadduct formation occurs across the 2- and 6-positions together with N-phenylation. 1-Methyl-3-oxidopyridinium and its 6-methyl analogue both react with 2 mol. equiv. of benzyne in two successive cycloadditions.
N. Dennis, A. R. Katritzky and S. K. Parton, J. Chem. Soc., Perkin Trans. 1, 1976, 2285 DOI: 10.1039/P19760002285
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