Issue 20, 1976

Oxidation of N-hydroxy-amines by sulphuryl chloride

Abstract

Reactions of N-hydroxy-amines with sulphuryl chloride in ether gave N-chloro-N-hydroxyammonium salts. Work-up of these salts with aqueous potassium hydroxide afforded nitrones or nitrosobenzenes, depending on the starting materials. Reactions in acetonitrile, in which the intermediate salts are soluble, yielded products of further reaction of the nitrones.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1976, 2202-2205

Oxidation of N-hydroxy-amines by sulphuryl chloride

M. Nojima, K. Takeuchi, E. Fukui and N. Tokura, J. Chem. Soc., Perkin Trans. 1, 1976, 2202 DOI: 10.1039/P19760002202

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