SCHEDULED MAINTENANCE
The 13C n.m.r. spectra of methyl 2-(3-hydroxy-2-methoxycarbonyl-4,5,6-trimethylphenyl)propionate (II) derived from the fungal metabolite sclerin (I) enriched with 13C from [1,2-13C]acetate or from [methyl-13C]-methionine, establish that the metabolite is derived from two β-ketide precursors with the introduction of three C-methyl groups from methionine.
R. E. Cox and J. S. E. Holker, J. Chem. Soc., Perkin Trans. 1, 1976, 2077 DOI: 10.1039/P19760002077
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