Issue 16, 1976

Stereochemistry of iodofluorination of phenyl-substituted olefins with (difluoroiodo)methane

Abstract

(Difluoroiodo)methane reacts with substituted olefins, e.g. cis- and trans-stilbene, cis- and trans-β-alkylstyrenes, and indene, to form the corresponding iodo-fluorides. Iodofluorination proceeds with Markovnikov-type regioselectivity and is stereospecifically anti, forming the corresponding (±)-erythro- or (±)-threo-1-fluoro-2-iodo-1-phenylethanes.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1976, 1745-1748

Stereochemistry of iodofluorination of phenyl-substituted olefins with (difluoroiodo)methane

M. Zupan and A. Pollak, J. Chem. Soc., Perkin Trans. 1, 1976, 1745 DOI: 10.1039/P19760001745

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