Phenyl benzenesulphonate (7) gives benzyne when treated with lithium tetramethylpiperidide (9). The yields of various benzyne-derived products are not as high as when bromobenzene is used to generate the benzyne. Such benzyne as is produced comes entirely from the aromatic ring derived from the phenol.
I. Fleming and T. Mah, J. Chem. Soc., Perkin Trans. 1, 1976, 1577 DOI: 10.1039/P19760001577
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