With the aid of circular dichroism, n.m.r. shift reagents, and 13C n.m.r. spectroscopy the absolute stereochemistry has been assigned to avarol {2-[(1R)-1,2,3,4,4a,7,8,8aα-octahydro-1β,2β,4aβ,5-tetramethyl-1-naphthylmethyl]-hydroquinone}, obtained from the marine sponge Disidea avara. Avarol is the first naturally occurring sesquiter-penoid of the 9,4-friedodrimane type to be isolated.
S. de Rosa, L. Minale, R. Riccio and G. Sodano, J. Chem. Soc., Perkin Trans. 1, 1976, 1408 DOI: 10.1039/P19760001408
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...