The biosynthetic sequence trichodermol (2)→ 12,13-epoxy-4β,8-dihydroxytrichothec-9-ene (3)→ trichothecolone (4)→ trichothecin (5) in Trichothecium roseum has been established. Earlier evidence suggesting the intervention of crotocin (6) has not been substantiated.
R. Evans, J. R. Hanson and T. Marten, J. Chem. Soc., Perkin Trans. 1, 1976, 1212 DOI: 10.1039/P19760001212
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