Several pin-2-ene derivatives substituted at C-4 were prepared. ortho-Menthenes were produced from these by cleavage of the 5,C-bond in reactions which proceed through C-4 carbocations.
N. Lander and R. Mechoulam, J. Chem. Soc., Perkin Trans. 1, 1976, 484 DOI: 10.1039/P19760000484
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