Elenolic acid (2c) has been obtained from secologanin (1a) in accord with its proposed derivation by rearrangement of an aglycone, and converted into ajmalicine (8c), 19-epi-ajmalicine (8a), and tetrahydroalstonine (8b).
R. T. Brown, C. L. Chapple, D. M. Duckworth and R. Platt, J. Chem. Soc., Perkin Trans. 1, 1976, 160 DOI: 10.1039/P19760000160
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