In this paper arguments are advanced advocating the introduction of a continuum collective coordinate representation of the highly excited anharmonic vibrational states of molecules. The structure of the vibrational spectrum is considered and an illustrative example is examined; the example is that of a simple unimolecular rearrangement reaction.
P. P. Schmidt, J. Chem. Soc., Faraday Trans. 2, 1976, 72, 1074 DOI: 10.1039/F29767201074
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