Issue 0, 1976
From the journal:

Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases

Conductance of some cobalt(III) complexes in water at 25°C. Part 1.—Conductance of salts of trans- and cis-dinitrobis(ethylenediamine)cobalt(III)

Alan D. Pethybridge  and  David J. Spiers  

Abstract

Precise conductivity results are reported for aqueous solutions of seven salts of trans- and cis-[Co(en)2(NO2)2]+. They are analysed in terms of the full Pitts equation and the association constants for the salts, although small, are found to increase with increasing radii of the ions, being particularly large for cis-[Co(en)2(NO2)2]I. Contrary to popular belief, trans-[Co(en)2(NO2)2]ClO4 is also appreciably associated in dilute aqueous solution. Rate constants for the very slow aquation of these cations are also reported.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/F19767200064
Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1976,72, 64-72

Permissions

Request permissions

Conductance of some cobalt(III) complexes in water at 25°C. Part 1.—Conductance of salts of trans- and cis-dinitrobis(ethylenediamine)cobalt(III)

A. D. Pethybridge and D. J. Spiers, J. Chem. Soc., Faraday Trans. 1, 1976, 72, 64 DOI: 10.1039/F19767200064

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements