Issue 23, 1976
From the journal:

Journal of the Chemical Society, Dalton Transactions

Synthesis, fluxional behaviour, and oxidative-addition reactions of some µ-alkylthio-diplatinum(II) complexes

Michael P. Brown,   Richard J. Puddephatt  and  Clive E. E. Upton  

Abstract

A series of complexes cis-[Pt2X2(PMe2Ph)2(µ-SMe)2](X = Cl, I, Me, or Ph) and cis-[Pt2X2(PMe2Ph)2(µ-SEt)2](X = Cl or Me) has been prepared. The complexes undergo a fluxional process thought to involve inversion at the bridging sulphur atoms. and the rate is strongly dependent on the group X. Reactions of the complexes with X = Me or Ph with methyl iodide are complicated and involve oxidative-addition–reductive-elimination sequences to give monomeric organoplatinum complexes as the final products.

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Article information

DOI
https://doi.org/10.1039/DT9760002490
Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 2490-2494

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Synthesis, fluxional behaviour, and oxidative-addition reactions of some µ-alkylthio-diplatinum(II) complexes

M. P. Brown, R. J. Puddephatt and C. E. E. Upton, J. Chem. Soc., Dalton Trans., 1976, 2490 DOI: 10.1039/DT9760002490

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