Alkylimido-complexes [ReCl3(NR)(PR′3)2](PR′3= tertiary phosphine) react with bases such as pyridine to yield methyleneamido-complexes, which contain the group –N![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHR (R = H or alkyl). Acids reconvert the methylene-amido-complexes into alkylimido-complexes.
J. Chatt, R. J. Dosser, F. King and G. J. Leigh, J. Chem. Soc., Dalton Trans., 1976, 2435 DOI: 10.1039/DT9760002435
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