Issue 19, 1976

Thermochemistry of tris(l,1,1 -trifluoropentane-2,4-dionato)- and tris(2,2,6,6-tetramethylheptane-3,5-dionato)-aluminium(III)

Abstract

Enthalpies of formation of the crystalline title complexes have been determined at 298.15 K by solution calorimetry: ΔHf[Al(tfpd)3(c)]=–892.7 ± 3.1 and ΔHf[Al(tmhd)3(c)]=–571.5 ± 3.1 kcal mol–1. Gas-phase enthalpies have been calculated, and from these the Al–O bond energies have been derived.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1976, 1940-1942

Thermochemistry of tris(l,1,1 -trifluoropentane-2,4-dionato)- and tris(2,2,6,6-tetramethylheptane-3,5-dionato)-aluminium(III)

R. J. Irving and M. A. V. R. da Silva, J. Chem. Soc., Dalton Trans., 1976, 1940 DOI: 10.1039/DT9760001940

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