The 13C n.m.r. spectra of fluorophosphoranes containing the perfluoropinacolyl (pfp) ring system are reported: PRF2(pfp)[R = F, Me, But, Ph, NEt2, or N(SiMe3)2] and N2(SiMe3)2P2F2(pfp)2. The results are consistent with previously reported 19F n.m.r. studies and give evidence for a two-stage intramolecular exchange process.
J. A. Gibson and G. Röschenthaler, J. Chem. Soc., Dalton Trans., 1976, 1440 DOI: 10.1039/DT9760001440
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...